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1,4-Additions of tricyclic 1,4-diphosphinines – a novel system to study pi-bond activation and  dispersion interactions

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Tartalom: http://real.mtak.hu/91191/
Archívum: REAL
Gyűjtemény: Status = Published
Subject = Q Science / természettudomány: QD Chemistry / kémia: QD03 Inorganic chemistry / szervetlen kémia
Type = Article
Cím:
1,4-Additions of tricyclic 1,4-diphosphinines – a novel system to study pi-bond activation and  dispersion interactions
Létrehozó:
Koner, Abishek
Kelemen, Zsolt
Schnakenburg, Gregor
Nyulászi, László
Streubel, Rainer
Kiadó:
Royal Society of Chemistry
Dátum:
2018-01-12
Téma:
QD03 Inorganic chemistry / szervetlen kémia
Tartalmi leírás:
The dienic nature of the aromatic π-system in 1,4-diphosphinines remained largely unexplored to this day due to a lack of facile and efficient synthetic protocols. Recently reported stable, tricyclic 1,4-diphosphinines were used to explore the thermal reactivity of the π-system towards an array of dienophiles in [4π+2π]- and, for the first time, in [4π+2σ]-type cycloaddition reactions.
Nyelv:
angol
Típus:
Article
NonPeerReviewed
info:eu-repo/semantics/article
Formátum:
text
Azonosító:
Koner, Abishek and Kelemen, Zsolt and Schnakenburg, Gregor and Nyulászi, László and Streubel, Rainer (2018) 1,4-Additions of tricyclic 1,4-diphosphinines – a novel system to study pi-bond activation and  dispersion interactions. CHEMICAL COMMUNICATIONS. pp. 1182-1184. ISSN 1359-7345
Kapcsolat:
DOI: 10.1039/c7cc09349g